A new route for the synthesis of binuclear organometallic and inorganic palladium(II) complexes

  1. Usón, R. 1
  2. Forniés, J. 1
  3. Navarro, R. 1
  4. Garcia, M.P. 1
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

Revista:
Inorganica Chimica Acta

ISSN: 0020-1693

Año de publicación: 1979

Volumen: 33

Número: C

Páginas: 69-75

Tipo: Artículo

DOI: 10.1016/S0020-1693(00)89456-6 SCOPUS: 2-s2.0-4243631062 GOOGLE SCHOLAR

Otras publicaciones en: Inorganica Chimica Acta

Resumen

A new generally applicable route for the preparation of binuclear organometallic palladium(II) complexes is described. Compounds of the general formula [Pd(μ-Cl)RL]2 (R being C6F5 or C6Cl5; L being a neutral ligand with N, P, As, Sb or S as donor atom) have been obtained by the reaction of organometallic compounds of the PdR2L2 type with PdCl2 in acetone solution at room temperature. The reaction with PdCl2 had also been used for the systhesis of inorganic palladium(II) derivatieves of the [PdCl2L]2 type. The structure of the novel organometallic complexes is discussed. © 1979.