Ring-Rearrangement Metathesis of 1-Substituted 7-Azanorbornenes as an Entry to 1-Azaspiro[4.5]decane systems
- Carreras, J. 1
- Avenoza, A. 1
- Busto, J.H. 1
- Peregrina, J.M. 1
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1
Universidad de La Rioja
info
ISSN: 0022-3263
Year of publication: 2011
Volume: 76
Issue: 9
Pages: 3381-3391
Type: Article
More publications in: Journal of Organic Chemistry
Abstract
Several metathesis sequences have been carried out using 7-azanorbornenes as starting materials. The occurrence of several exocyclic olefin patterns in the bridgehead position of this system opens the way to gain interesting spirocyclic compounds, which were achieved using several ring-rearrangement metatheses (RRM). The metathesis products, thus obtained, may be useful for the synthesis of new peptidomimetics and related compounds. © 2011 American Chemical Society.