Manuel
Temprado Morena
Profesor/a Titular Universidad
Tufts University
Medford, Estados UnidosPublications in collaboration with researchers from Tufts University (9)
2023
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Binding of Nitriles and Isonitriles to V(III) and Mo(III) Complexes: Ligand vs Metal Controlled Mechanism
Inorganic Chemistry, Vol. 62, Núm. 27, pp. 10559-10571
2018
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Ligand-Directed Reactivity in Dioxygen and Water Binding to cis-[Pd(NHC)2(η2-O2)]
Journal of the American Chemical Society, Vol. 140, Núm. 1, pp. 264-276
2014
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Role of axial base coordination in isonitrile binding and chalcogen atom transfer to vanadium(III) complexes
Inorganic Chemistry, Vol. 53, Núm. 20, pp. 11185-11196
2013
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Thermodynamic and kinetic study of cleavage of the N-O bond of N-oxides by a vanadium(III) complex: Enhanced oxygen atom transfer reaction rates for adducts of nitrous oxide and mesityl nitrile oxide
Journal of the American Chemical Society, Vol. 135, Núm. 30, pp. 11357-11372
2012
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Two-step binding of O 2 to a vanadium(III) trisanilide complex to form a non-vanadyl vanadium(V) peroxo complex
Journal of the American Chemical Society, Vol. 134, Núm. 44, pp. 18249-18252
2011
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Oxygen binding to [Pd(L)(L′)] (L= NHC, L′ = NHC or PR 3, NHC = N -heterocyclic carbene). Synthesis and structure of a paramagnetic trans -[Pd(NHC)2(η1-O2) 2] complex
Journal of the American Chemical Society, Vol. 133, Núm. 5, pp. 1290-1293
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Thermodynamic, kinetic, and mechanistic study of oxygen atom transfer from mesityl nitrile oxide to phosphines and to a terminal metal phosphido complex
Inorganic Chemistry, Vol. 50, Núm. 19, pp. 9620-9630
2009
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Coordination-mode control of bound nitrile radical complex reactivity: Intercepting end-on nitrile-mo(III) radicals at low temperature
Journal of the American Chemical Society, Vol. 131, Núm. 42, pp. 15412-15423